Neutralisation and other reactions of acids — pH and indicators
Two of the most common types of compounds we meet every day are acids and bases. Today we learn what makes a substance acidic or basic at the particle level (H⁺ vs OH⁻), the pH scale that measures it, and the indicators that reveal it.
Learning Intentions + Success Criteria
LITo classify a substance as acidic or basic using pH and indicators.
SC: I can:
01I can explain that acids release H⁺ ions and bases release OH⁻ ions in water.
02I can read the pH scale (0–14) and classify a solution as acidic, neutral, or basic.
03I can predict the colour change of universal indicator and litmus across the pH range.
01
Engage
5 min
↺Quick recap · from last class
L9 · Recap — synthesis, decomposition, and displacement reactions
Try these 3questions before today's new content. Click an answer for instant feedback — your teacher will walk through them with you.
The video showed how universal indicator changes colour across the pH scale. Predict: a few drops of universal indicator are added to each of three colourless liquids — vinegar, soapy water, and distilled water. What colour would each turn, and what does that tell you about each liquid's pH?
02
Explicit
17 min
Today's procedure — classify a solution by pH
START — you have an unknown solution
↓
1. Pick a measurement tool
Digital pH meter — reads the exact pH number Indicator — match the colour to a chart
↓
2. Read the value (or colour)
↓
3. Compare to neutral (pH 7)
↓
↓ pH < 7
ACIDIC more H⁺ ions in solution (read: “hydrogen ions”) e.g. lemon juice, vinegar
↓ pH = 7
NEUTRAL [H⁺] = [OH⁻] (equal hydrogen ions and hydroxide ions) e.g. pure water
↓ pH > 7
BASIC / ALKALINE more OH⁻ ions in solution (read: “hydroxide ions”) e.g. soap, ammonia
One skill for today: given any solution, classify it as acidic, neutral, or basic.
Acid vs base — at a glance
AcidpH < 7
Releases H⁺ ions (hydrogen ions) in water.
Corrosive — can burn skin and eyes; sour taste in food.
Memory hook: Acid → H⁺ · Base → OH⁻. Every alkali is a base, but not every base is an alkali (only the dissolved ones).
Acids and bases are everywhere
Two of the most commonly occurring groups of compounds are acids and bases. They are found in many everyday items and places, such as cleaning products, swimming pools and kitchens. Many of the foods we eat are also either acidic or basic, and these properties help with digestion. Acids can be dangerous because they are corrosive, and they can react with some metals to produce hydrogen gas and metallic salts. However, when an acid and a base react together, they neutralise each other, forming products that are usually much safer.
ACIDIC
Lemons
Tomatoes
Berries
BASIC
Eggs
Bananas
Spinach
Soybeans
Figure 4.14 — Weak acids and bases occur naturally in many of the foods we eat every day.
Acids produce hydrogen ions
An acid is a corrosive chemical substance that produces hydrogen ions (H⁺) when mixed with water. The hydrogen ions can react with other substances to produce water and hydrogen gas, as well as ionic salts, which are made up of cations and anions.
The higher the concentration of hydrogen ions produced by an acid, the higher its acidity. Strong acids are very dangerous, especially when they contact skin and eyes. That is why you must always wear protective clothing and eyewear when working with acids in the laboratory.
Weak acids are important in our diet. Citrus fruits contain a weak acid, called citric acid, which contributes to their sour flavour. Soft drinks, coffee and vinegar also contain weak acids.
Bases produce hydroxide ions
A base is a substance that reacts with an acid to neutralise it. Bases that dissolve in water are called alkalis. When mixed with water, bases produce hydroxide ions (OH⁻) — an atom of oxygen bonded to an atom of hydrogen, with an overall negative charge.
Strong bases are described as caustic, meaning they cause burns by chemical action; therefore, they can be just as dangerous as acids. Bases such as sodium hydroxide and ammonia react with oils and fats and so are used in many household cleaners. Weak bases are found in toothpaste, conditioners, antacid tablets and baking powder.
Three common types of substances act as bases:
Metal hydroxides (e.g. potassium hydroxide) contain metals bonded with hydroxide (OH⁻).
Metal oxides (e.g. zinc oxide) contain metals bonded with oxide ions (O²⁻).
Metal carbonates (e.g. copper carbonate) contain metals bonded with carbonate ions (CO₃²⁻).
The pH scale measures acidity
The acidity of a solution is measured on a scale called the pH scale (Figure 4.15). The higher the proportion of H⁺ ions, the lower the pH. The lower the proportion of H⁺ ions in a solution compared to hydroxide ions (OH⁻), the higher the pH. Acids have a low pH, while bases have a high pH. A solution with a pH of 7 is neutral, a solution with a pH of less than 7 is acidic, and a solution with a pH greater than 7 is basic. Pure water is neutral because it has a pH of 7 at 25 °C.
You can measure pH by using a digital pH meter, or by adding an indicator to a solution and matching its colour to a chart. Indicators change colour depending on whether they are mixed with an acid or a base. A common indicator is litmus, which turns red when mixed with acids and blue when mixed with bases.
Figure 4.15 — the pH scale (with everyday examples):
pH
Class
Everyday example
0
Strongly acidic
Battery acid
1
Acidic
Stomach acid
2
Acidic
Lemons
3
Acidic
Vinegar
4
Acidic
Acid rain
5
Weakly acidic
Clean rain
6
Weakly acidic
Milk
7
Neutral
Pure water
8
Weakly basic
Eggs
9
Basic
Bicarbonate of soda
10
Basic
Milk of magnesia
11
Basic
Ammonia-based cleaning products
12
Strongly basic
Household bleach
13
Strongly basic
Oven cleaner
14
Strongly basic
Drain cleaner
Indicators can be used to measure pH
Different indicators show a wide range of colour changes depending on the pH of a solution. For example, a universal indicator can show multiple colours to indicate the pH from 1 to 14, from red in strong acids to violet in strong bases (Figure 4.16):
pH 037 (neutral)11pH 14
← MORE ACIDICMORE BASIC →
Figure 4.16 — Universal indicator colour change across pH 0–14: red (strong acid) → orange → yellow → green (neutral) → blue → violet (strong base).
Some indicators display only two or four colours throughout the pH range. This can be useful when we are only concerned about whether a substance is above or below a certain pH. Figure 4.17 shows a variety of different indicators and their colour changes at specific pH values. For example, bromocresol green changes from yellow to blue at pH 4–5, so it would not be able to identify with certainty if a solution is basic (alkaline), though it could identify if its pH is above or below 4–5.
YouTube · Indicators in acid–base chemistry — universal, methyl orange, bromothymol blue, phenolphthalein · open in new tab
Watch the indicators flip in real time, then use the chart below as your reference whenever you need to recall what each one looks like at a given pH.
Indicator
pH 03711pH 14
Thymol blue
flips ~ pH 1.2–2.8 then 8.0–9.6
Methyl orange
flips ~ pH 3.1–4.4
Bromocresol green
flips ~ pH 3.8–5.4
Methyl red
flips ~ pH 4.4–6.2
Bromothymol blue
flips ~ pH 6.0–7.6
Phenolphthalein
flips ~ pH 8.3–10.0
Litmus
flips ~ pH 4.5–8.3
Universal indicator
full 0–14 scale
← MORE ACIDICNEUTRALMORE BASIC →
Figure 4.17 — Colour transitions for eight common pH indicators across the 0–14 scale. The first seven flip across a narrow pH window — useful when you only need to know if a solution is above or below a specific pH. Universal indicator is the only one that gives a distinct colour for every step.
Key terms
Keywords
acid
A substance with a pH of less than 7.
alkali
A base that is dissolved in water.
base
A substance with a pH of more than 7.
caustic
Able to burn or corrode organic tissue through chemical action.
concentration
The amount of a substance in a volume of solution.
corrosive
Highly reactive and damaging or destructive to another substance.
indicator
A substance used to determine the acidity of a solution.
neutralisation reaction
A reaction involving an acid and a base to produce water and a salt.
neutralise
To make something chemically neutral; neither acidic nor basic.
pH
A figure expressing the acidity or alkalinity of a solution.
We do — predict the indicators for an unknown solution
We do · whole class · 3 prompts
A student measures a sample with a pH meter and reads pH 9. Predict what each indicator will show.
Prompt 1 — where on the 0–14 scale, and what does that mean?
Prompt 2 — universal indicator colour?
Prompt 3 — what does litmus paper do?
⚠Watch out · common traps
1
Trap 1
“Low pH = weak acid.”
Wrong — pH and acid strength point in OPPOSITE directions.
The pH scale measures how many H⁺ ions are in solution: more H⁺ means a lower pH and a stronger acid. Lemon juice at pH 2 is much more acidic than milk at pH 6, and battery acid at pH 0 is the strongest of the three.
Rule: low pH = strong acid; high pH = strong base; pH 7 is the middle (neutral).
2
Trap 2
“Universal indicator gives an exact pH number.”
Wrong — universal indicator gives a colour BAND, not a number.
Universal indicator runs through six colours: red (pH ≈ 1–2) → orange (pH 3–4) → yellow (pH 5–6) → green (pH 7, neutral) → blue (pH 8–11) → purple (pH 12–14). Each colour covers a range of pH values.
If you need a precise reading like "pH 4.7", you must use a digital pH meter — not universal indicator.
Rule: universal indicator narrows the range; a pH meter gives the exact number.
3
Trap 3
“Litmus tells you how strong an acid is.”
Wrong — litmus is a two-colour indicator: red in acid, blue in alkali. That is the whole signal.
Lemon juice (pH 2), vinegar (pH 3) and concentrated HCl (pH 0) all turn litmus the same red. Litmus cannot distinguish weak from strong acids — it only tells you which side of pH 7 you are on.
Rule: litmus = acid vs alkali; universal indicator = rough pH; pH meter = exact pH.
03
Apply
25 min
Question 1Classify by pHQuestion 2Universal indicator colours
Starting from the most acidic end and moving up the pH scale, universal indicator runs from red to violet. Fill in the missing colours.
Question 3Identify the substance
▸Your turnShort answer · Have a go first
A student adds universal indicator to a sample of an unknown clear liquid. The solution turns blue. (a) Is the liquid acidic, neutral, or basic? (b) Roughly what pH range would you estimate? (c) Does the liquid have more H⁺ ions or more OH⁻ ions?
Question 4Match substance to pH
04
Catch
5 min05
Reflect
10 min
▸Your turnReflect · One thing you learned
One thing I now understand about pH or indicators that I didn't understand at the start of the lesson:
Success criteria — where are you right now?
Next class (Fri 8 May, P2): neutralisation — what happens when an acid meets a base.